Product ID:CHLORIDE INDICATOR
MSDS Date:06/27/1996
FSC:6810
NIIN:00-753-4907
MSDS Number: BFNDZ

CITY CHEMICAL CORP

132 WEST 22ND ST
NEW YORK, NY 10011
US

Emergency Phone: 800-424-9300

Info Phone: 800-424-9300

Preparer: PETER WOLPERT

Cage: 83628

CITY CHEMICAL CORPORATION

JERSEY CITY, NJ 07310 US

Telephone: 201-653-6900/800-248-2436

Cage: 83628

2-PHENYLHYDRAZINE

CAS: 538-62-5

RTECS: LQ9420000

Fraction By Weight: 92.6%

BROMOPHENOL BLUE

CAS: 115-39-9

RTECS: SJ7453000

Fraction By Weight: 7.4%

LD50 LC50 Mixture:NOT GIVEN
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF DUST MAY BE IRRITATION
TO THE RESPIRATORY TRACT. INGESTION MAY CAUSE IRRITATION TO THE
MOUTH AND GASTROINTESTINAL TRACT. MAY CAUSE EYE IRRITATION WITH
REDNESS AND PAIN. MAY CAUSE SKIN IR RITATION. LEAVES STAINS ON
SKIN.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION WITH REDNESS AND PAIN, SKIN
IRRITATION, LEAVES STAINS ON SKIN, RESPIRATORY TRACT IRRITATION,
SORE THROAT, COUGHING, LABORED BREATHING MOUTH IRRITATION, GI TRACT
IRRITATION.
Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING SKIN, EYES
AND RESPIRATORY TRACT DISORDERS SHOULD AVOID ALL EXPOSURE TO THIS
PRODUCT.

First Aid:EYES: WASH WITH PLENTY OF WATER FOR AT LEAST 15 MIN. CALL A
PHYSICIAN. SKIN: REMOVE ANY CONTAMINATED CLOTHING. WASH SKIN WITH
SOAP OR MILD DETERGENT AND WATER FOR AT LEAST 15 MIN. WASH
CONTAMINATED CL OTHING BEFORE REUSE. INHALATION: REMOVETO FRESH
AIR. ADMINISTER BREATHING SUPPORT MEASURES IF NEEDED. INGESTION: IF
SWALLOWED GIVE WATER OR MILK TO DRINK, IF CONSCIOUS. GET MEDICAL
ATTENTION.

Flash Point:NON-FLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER, DRY CHEMICAL, ALCOHOL FOAM OR CARBON
DIOXIDE.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF-CONTAINED
BREATHING APPARATUS AND STRUCTURAL FIREFIGHTER'S PROTECTIVE
CLOTHING TO PROVIDE LIMITED PROTECTION.
Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION, IT EMITS
TOXIC FUMES OF NITROGEN OXIDES, SULFUR OXIDES AND HYDROGEN BROMIDE
GAS.

Spill Release Procedures:1. VENTILATE AREA. 2. CLEAN-UP PERSONNEL
SHOULD WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND
HEAVY RUBBER GLOVES. 3. SWEEP UP AND PLACE IN A SUITABLE DOT WASTE
CONTAINER, REMOVE FROM ARE A. 4. WASH SPILL SITE AFTER MATERIAL
PICK-UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP THOROUGHLY AFTER HANDLING. AVOID
BREATHING DUST. USE ADEQUATE VENTILATION. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:USE A DUST/MIST RESPIRATOR WHEN CONDITIONS
WARRANT.
Ventilation:A LOCAL EXHAUST SYSTEM WHICH CAPTURES THE CONTAMINATE AT
ITS SOURCE IS RECOMMENDED TO PREVENT DISPERSION.
Protective Gloves:RUBBER GLOVES
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:EYEWASH FOUNTAIN AND QUICK-DRENCH FACILITIES
IN THE WORK PLACE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:N1
Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:M.P/F.P Text:302F,150C
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:NEGLIGIBLE
Vapor Density:NOT GIVEN
Spec Gravity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:SLIGHT
Appearance and Odor:ODORLESS ORANGE POWDER.
Percent Volatiles by Volume:NIL

Stability Indicator/Materials to Avoid:YES
STORNG OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:TOXIC FUMES OF NITROGEN OXIDES, SULFUR
OXIDES AND HYDROGEN BROMIDE GAS.

Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY MAY BE
BURNED IN AN APPROVED INCINERATOR OR DISPOSED IN AN APPROVED WASTE
FACILITY. DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.